Table II Comparison of QqQ SRM and QqOrbi PRM dynamic range and linearity
SRMPRM
±0.2 Th±1 Th
Means
    Neat
        # orders3.32.73.5
        %RSD42.0929.9927.36
        %RSDadj12.9711.807.72
    Matrix
        # orders2.22.42.9
        %RSD16.0929.9829.08
        %RSDadj8.0313.0710.49
p values (SRM vs. PRM)
    Neat
        # orders2.61E-02b1.89E-01
        %RSD2.33E-02a8.74E-04a
        %RSDadj2.38E-011.99E-05a
    Matrix
        # orders5.47E-012.77E-03a
        %RSD2.72E-02b3.08E-02b
        %RSDadj1.05E-015.11E-01
  • a PRM data show significantly greater linearity or dynamic range (α = 5E-02).

  • b SRM data show significantly greater linearity or dynamic range (α = 5E-02).